Polytropic Process

Any thermodynamic process, represented by a Gas Equation in terms of product of powers of parameters {P, V, T} equated to a constant is called a polytropic process.

For example-
(P^3)(V^5)=constant
(P^-1)(V^-3)(T^6)=constant
(P)(V^gamma)=constant...(yes, even the adiabatic one)
P=constant
V=constant, and so on

now, i take a general process (P^a)(T^b)=constant, or equivalently, (P)(T^b/a)=constant, calculate
1)molar heat capacity in terms of Cv, R, a, and b
2)coefficient of volume expansion in terms of instantaneous temperature T, a, and b
3)bulk modulus in terms of instantaneous pressure P, a, and b
and
4)learn if possible..(the resemblance in the 3 is uncanny, and always saves up maths and calculations worth 2 mins during the exam, a double treat if this equation comes in a paragraph!)

now, if someone comes up with a process (P^l)(V^m)(T^n)=constant, use the ideal gas equation to convert it in the form (P^a)(T^b)=constant, and then use the formulae we learnt :-)



-Sambhav

5 comments:

  1. 1] Ceq= Cv+R{1+a/b}

    2]coefficient of volume expansion= {1/T}{1+b/a}

    3]bulk modulus= P/{1+a/b}

    ReplyDelete
  2. shaan, you are a bit wrong in Ceq

    ReplyDelete
  3. Ceq = Cv + R(1 + b/a)
    Coeff. of volume exp. = (1 + b/a)/T
    Bulk modulus = P/(1 + a/b)

    ReplyDelete